Packet 1: Bonus 1
Phenyl iso·thio·cyanate is converted to phenylthiohydantoin (“phenyl-thio-hy-DAN-toh-in”) in a method for this task named for a Swedish chemist. For 10 points each:
[10m] Name this task that can be performed with the now-outdated Edman degradation. Tandem mass spectrometry is commonly used in “top-down” and “bottom-up” approaches to this task.
ANSWER: protein sequencing [or polypeptide sequencing; accept descriptions of determining amino acid order in a protein; prompt on sequencing]
[10h] Protein sequencing via the Edman degradation does not work if the N-terminus is modified, such as the addition of these lipids onto a glycine residue via NMTs, during which they adopt a question-mark-shaped conformation. The name of these lipids is derived from the Latin name of nutmeg.
ANSWER: myristoyl (“my-RIST-oil”) groups [or myristic acid or myristate; accept tetradecanoic acid or tetradecanoyl]
[10e] Dyes exhibiting this phenomenon label amino acids in the Edman degradation. In this phenomenon, a molecule absorbs and reemits light at a longer wavelength on a shorter timescale than phosphorescence.
ANSWER: fluorescence
<Waterloo, Chemistry> | A. Prelims 1 - Waterloo + Toronto A + Georgia Tech B
| Heard | PPB | E % | M % | H % |
|---|---|---|---|---|
| 22 | 12.27 | 96% | 23% | 5% |
Conversion
| Team | Opponent | Part 1 | Part 2 | Part 3 | Total | Parts |
|---|---|---|---|---|---|---|
| Bruin | Toronto B | 0 | 0 | 10 | 10 | E |
| Cambridge | Rutgers | 10 | 0 | 10 | 20 | ME |
| Chicago B | Georgia Tech C | 0 | 0 | 10 | 10 | E |
| Columbia A | UC Berkeley A | 0 | 0 | 10 | 10 | E |
| Columbia B | MIT | 10 | 0 | 10 | 20 | ME |
| Georgetown | Georgia Tech A | 0 | 0 | 10 | 10 | E |
| Harvard | Chicago A | 0 | 0 | 10 | 10 | E |
| Indiana | Maryland A | 10 | 0 | 10 | 20 | ME |
| Johns Hopkins | NYU A | 0 | 0 | 10 | 10 | E |
| Minnesota | Maryland B | 0 | 0 | 10 | 10 | E |
| North Carolina | UCF | 0 | 0 | 10 | 10 | E |
| Northwestern A | Michigan | 10 | 0 | 10 | 20 | ME |
| Northwestern B | Stanford B | 0 | 0 | 0 | 0 | |
| Ohio State | Texas | 0 | 0 | 10 | 10 | E |
| Penn State | UCLA | 0 | 0 | 10 | 10 | E |
| Pittsburgh | Cornell | 0 | 0 | 10 | 10 | E |
| Stanford A | Illinois B | 10 | 0 | 10 | 20 | ME |
| Swarthmore | WashU | 0 | 0 | 10 | 10 | E |
| UC Berkeley B | Illinois A | 0 | 0 | 10 | 10 | E |
| Vanderbilt | Brown | 0 | 0 | 10 | 10 | E |
| Virginia | British Columbia | 0 | 0 | 10 | 10 | E |
| Virginia Tech | Purdue | 0 | 10 | 10 | 20 | HE |
Summary
| Tournament | Edition | Match | Heard | PPB | E % | M % | H % |
|---|---|---|---|---|---|---|---|
| Main Site | 2026-04-17 | ✓ | 22 | 12.27 | 96% | 23% | 5% |